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51.
预压缩单晶镍基合金的组织结构及在拉伸蠕变期间的粗化特征 总被引:1,自引:1,他引:1
对[001]取向单晶镍基合金进行压应力处理,获P-型筏状结构后,对其进行拉伸蠕变性能测试及SEM形貌观察,研究了P-型筏状结构的粗化特征及影响因素。结果表明:由于应力场的差别,样品不同位置筏状γ'相粗化程度及特征不同,近断口处筏状γ'相扭曲且粗化程度加剧,随离断口距离增加,γ'相粗化程度减弱。有限元分析认为:外加载荷改变了水平和垂直γ基体通道中的错配应力分布,并使立方γ'相不同界面晶格发生挤压或扩张应变,这可以促进元素的互扩散和γ'相的定向生长,是形成P-型筏状组织的主要原因。在高温及拉应力作用下,P-型γ'相端部沿垂直于应力轴方向优先生长和相互横向连接,并进一步形成折叠的层状组织。 相似文献
52.
The combined erosion-oxidation of nickel, cobalt, and the oxides of these metals have been studied at 780°C in air to examine two regimes of interactionnamely, a regime of erosion-enhanced oxidation during which an oxide scale of constant thickness covers metal specimens, and a regime of oxidation-affected erosion that is characterized by a composite surface layer of metal, oxide, and erodent. In the case of cobalt, these two regimes have been documented and the transition from one regime to another described. For the range of conditions examined, only the oxidation-affected erosion regime was observed for nickel due to its lower oxidation rate compared to cobalt. 相似文献
53.
Phosphorus was added to Fe-50 wt.% Ni in the form of a coated composite powder via an electroless plating process. Addition
of phosphorus to Fe-50 wt.% Ni facilitated increases in density and grain size, both of which were beneficial to magnetic
performance. Because of the homogeneous distribution of phosphorus in the powder, the optimal phosphorus addition was much
lower than for those using Fe3P as the phosphorus precursor. The optimal phosphorus addition was close to its maximum solubility in Fe-50 wt.% Ni (about
0.5 wt.%), above which precipitation of excessive phosphorus in the form of iron nickel phosphide, (Fe,Ni)3P, effectively degraded the magnetic properties of Fe-50 wt.% Ni. Without the addition of phosphorus, good magnetic properties
could be achieved only when the sintering temperature was high enough (>1200 °C) to result in a high sintered density and
large grains in the sintered structure. 相似文献
54.
根据已知镍基合金成分和γ′相成分,运用分层宽容多目标优化法,分别计算了γ相成分及γ′相含量.优化测算过程的实现是通过建立使杠杆定律等式两端数值差最小和两相共格错配度最小的目标函数,并通过设置γ′相含量和基体相成分取值范围的约束条件而实现的.验证了该方法的可行性和准确性. 相似文献
55.
NICKEL ELECTROPLATING has been practicallyused for decades.There is an unknown part in theplating,although this is easy to plate.Applications ofthe plating are described from the practical viewpoint.Purpose of Nickel Electroplating(1)Decorative,and corrosion resistanceNickel electroplating is deposited on iron,cupper,zinc and aluminum substrate etc.,and chromiumplating is usually deposited on nickel plating.Hexavalent chromium plating has an important effecton the corrosion resisitan… 相似文献
56.
金属镍电沉积中枝晶分形生长的研究 总被引:5,自引:4,他引:5
将分形几何与电化学原理相结合,通过改进的有限扩散凝聚模型(diffusion-limited aggregation,DLA),采用基于Microsoft Visual C 6.0的Open GL编程,对点电极为阴极进行二维电沉积时沉积产物的形貌进行了模拟.以环形金属镍为阳极,石墨为阴极,用自行设计的试验设备制备了二维的金属镍枝晶以验证模拟结果.结果表明,在保持电压恒定的条件下,镍沉积层的形貌特征为具有分形结构的枝晶,这与采用DLA模型模拟所得的二维枝晶形貌具有相似性,表明该模型对枝晶电沉积的实验研究具有很好的指导意义. 相似文献
57.
K.M. Shaju V. Ganesh Kumar S. Rodrigues N. Munichandraiah A.K. Shukla 《Journal of Applied Electrochemistry》2000,30(3):347-357
Electrochemical studies on AB2 type Zr0.5Ti0.5V0.6Cr0.2Ni1.2 metal hydride electrodes with varying particle size suggests that the electrodes with alloy particles of about 60 m yield the optimum performance. The values for diffusion coefficient of hydrogen in the alloy particles > 25 m are found to be nearly invariant. Both a.c. impedance and linear polarization data on electrodes with varying particle size suggest that the charge-transfer resistance depends on state-of-charge of the electrodes. A comparison of scanning electron micrographs of fresh electrodes and subsequent to their prolonged charge-discharge cycling suggests that the metal hydride particles develop stress-induced cracks owing to their inherent expansion and contraction during the hydriding/dehydriding processes. 相似文献
58.
本文介绍了TFC?-S型纳滤膜分离电镀镍漂洗水的试验研究,讨论了温度、操作压力、浓差极化、共存离子对膜分离性能的影响。结果表明,这种纳滤膜对电镀镍漂洗水中Ni2 的去除率高于99.5%,透过液中Ni2 质量浓度小于1mg/L;对CODCr的去除率大于96%,透过液中CODCr低于14mg/L,达到国家工业废水排放标准(GB8978-1996),可以直接排放或回用于镀件漂洗。 相似文献
59.
The catalytic partial oxidation of CH4 to syngas was carried out over an Ni–Mg/Al mixed-oxide catalyst prepared from layered double hydroxide-type precursors. The catalysts were characterized by XRD, TPR, UV-DRS, XRF, BET and CHNS analysis. The effects of the catalyst composition and the calcination temperature on the catalytic performance and the extent of catalyst deactivation were investigated. Ni–Mg/Al oxide catalysts converted CH4 into syngas efficiently with high selectivity. The catalyst performance was strongly related to the Ni particle size and the calcination temperature. The catalysts that were calcined at higher temperature exhibited a better catalytic performance. In conclusion, the NiAl2O4 spinel phase had a positive effect on the stability of the catalyst. 相似文献
60.
We have applied near-edge X-ray absorption fine structure (NEXAFS) to characterize the surface and bulk properties of LixNi1–xO catalysts. In our experimental set-up, NEXAFS spectra of powder materials could be obtained by measuring the intensity of either electron-yield or fluorescence-yield. While the electron-yield method is sensitive only to the top few atomic layers, the fluorescence-yield method can detect species up to a few thousands angstroms deep into the bulk structure. The ability to distinguish surface and bulk compositions is demonstrated in studies of a number of Li0.5Ni0.5O samples, of which the surface compositions vary as a function of preparation procedures. In addition, NEXAFS investigations following the reaction of LixNi1–xO with CH4 have also been carried out and the results indicate that the initial surface reaction intermediates are Li2CO3. 相似文献